Your single best leveling method is getting all the exp boosters you have on time for Urgent Quests. Specially cradle of darkness. (Exp Boost, Triboost, Full Party, Medical drinks, etc)
Outside that, you can just unlock missions and client orders all the way up to Super Hard, specially explorations, which you want the access to the most if you're solo.
Speaking of solo, your second best leveling method is batch completing client orders. Stock on all the ones you can possible do in, for example, a single Forest Exploration run, then turn in and proceed with a batch of orders for the next exploratiom area.
This is even better once you unlock SH, as an additional "defeat 70 enemies" set of client orders is unlocked, which stacks with the "defeat 60 enemies" set.
If you can do Very Hard, you can do the client order method.