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By default Circle is set to Access/Cancel:

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Just like on Keyboard, Access lets you interact with objects/terminals/etc. (And pick up items.) This is why it has no function.

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@Golden_Syrup said in The Circle Button Is Vacant During Combat (Using A Pad ) What Could This Extra Button Be Used For.:

@coldreactive When Not Accessing Anything I.e On The Field

Not possible, since you have to be able to pick up items. One of the biggest strategies in this game is to use a --mate item as a Health pickup, rather than stock them.