How do you equip power shot after you have speced into it?
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Do you mean the Ranger Skill "Power Bullet"? If so, then it automatically activates for 30 seconds when you load a Special Round/Bullet (like "Blight Rounds" or "Jellen Shot") from your subpalette.
@AndrlCh Yes that was very helpful. I don’t understand why it lets you spec into that without having one of those.